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Beilstein J. Org. Chem. 2017, 13, 1106–1118, doi:10.3762/bjoc.13.110
Graphical Abstract
Figure 1: Build-couple-pair (B/C/P) strategy for macrocycles.
Figure 2: Different building blocks used for DOS.
Scheme 1: Cycloaddition reaction of alkyne-azide building block.
Scheme 2: Acetylation of macrocycle 4m.
Beilstein J. Org. Chem. 2013, 9, 775–785, doi:10.3762/bjoc.9.88
Scheme 1: Illustrative examples of a synthetic approach to natural-product-like molecules with over eighty mo...
Scheme 2: Overview of the proposed synthetic approach. FDIPES = diisopropyl(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10...
Figure 1: Structures of building blocks used in this study. Panel A: fluorous-tagged initiating building bloc...
Scheme 3: Synthesis of the initiating building blocks 6a and 6b. TBD = 1,5,7-triazabicyclo[4.4.0]dec-5-ene.
Scheme 4: Synthesis of the initiating building block 7.
Scheme 5: Fate of the metathesis reaction of the substrate 32.